Hi Kiki, welcome to roses. You can put coffee grounds on your roses just about any time except down in the fall. They are a nitorgen source that is good for the roots, stems, and blooms.
But you should not fertilize in fall with nitrogen because that will encourage top growth and blooms. Then if you get a freeze, you'll lose all that new growth and could lose the canes as well. In fall it's best to not fetilize, but maintain the watering schedule to encourage root development.
Cheryl

Thanks, Cheryl. I have lots of coffee grounds right now that I can use around them.

Yes, clip or snap off the faded blooms, it is called "deadheading". Here is an article about the "snapping" technique Never heard of pruning technique.

You don't want to fertilize in the fall as Cheryl says. I stop fertilizing in mid- to late-August.

Two very good books are The Organic Rose Garden by Liz Druitt and Foolproof Guide to Growing Roses by Field Roebuck.

Thanks so much for your help!
Kiki